Institute of Chemistry of the Academy of Sciences of Moldova Larisa Postolachi chemjm_correspondence@yahoo.com mEDRA 20161225

07 10.19261/cjm.2016.11(1).12 http://www.cjm.asm.md/sites/default/files/article_files/ChemJMold201611(1)_91-96_Bakalinska.pdf Institute of Chemistry of the Academy of Sciences of Moldova mEDRA 01 Institute of Chemistry of the Academy of Sciences of Moldova MD 07 1857-1727 JB 07 2345-1688 JD 11 1 June 2016 01 201606 12 11 91 96 6 1 A01 Daryna Haliarnik Haliarnik, Daryna Daryna Haliarnik 2 A01 Oleg Petuhov Petuhov, Oleg Oleg Petuhov 3 A01 Olga Bakalinska Bakalinska, Olga Olga Bakalinska 4 A01 Tudor Lupascu Lupascu, Tudor Tudor Lupascu 5 A01 Mykola Kartel Kartel, Mykola Mykola Kartel 01 eng 20 carbon nanomaterials; activated carbon; benzoyl peroxide; catalytic activity; Michaelis constant 01 The catalytic activities of nanoporous carbon materials, their modified forms and enzyme catalase was determined by calculation of Michaelis constants according to the kinetics of substrate decomposition. It is found that the catalytic activity of studied samples correlated with surface basicity and presence of quaternary nitrogen groups in structure. 201606 2016 Institute of Chemistry of the Academy of Sciences of Moldova 10.1016/S0008-6223(98)00235-8 10.1016/S1003-9953(06)60030-3 10.1021/la011320e 10.1590/S0104-66322010000100016 10.1021/la0004810 10.1016/j.watres.2015.01.018 10.1021/es0481169 10.1080/01496398008055619 10.1016/0043-1354(91)90175-P 10.1021/es803268b 10.1016/S1872-2067(10)60166-0 10.1016/j.apsusc.2011.10.062 Klimova, V.A. Basic Micromethods of Organic Compounds Analysis. Moscow: Khimia, 1967, 208 p. (in Russian) Alekseev, V.N. Quantitative Analysis. Moscow: Khimia, 1972, 504 p. (in Russian) 10.1016/S0008-6223(01)00165-8 Glevatska, K.V.; Bakalinska, O.M.; Kartel, M.T. The study, description and comparison of catalase activity of carbon sorbents of SKN and KAU type. Scientific notes of NaUKMA, Chemical Science and Technology, 2008, 79, pp. 19–23 (in Ukrainian) Strelko, V.V.; Nemoshkalenko, V.V.; Kartel, N.T.; Medvedev, S.L. On the state of the nitrogen atoms in the graphite lattice of activated carbons. Adsorption and Adsorbents, 1983, 11, pp. 76–80 (in Russian) Haliarnik, D.M.; Bakalinska, O.M.; Palyanytsya, B.B.; Kulyk, T.V.; Kartel, M.T. Organic Peroxides Decomposition by Carbon Nanomaterials in Nonaqueous Media. Surface, 2015, 7(22), pp. 253-263 (in Ukrainian) 10.1016/j.cattod.2014.10.033